Tytuł:

Ferric hydroxide-based media for removal of toxic arsenic species. Kinetic, equilibrium and thermodynamic studies

Tytuł publikacji grupowej:

Environment Protection Engineering

Autor:

Szlachta, Małgorzata ; Wójtowicz, Patryk

Współtwórca:

Majewska-Nowak, Katarzyna Maria. Redakcja

Temat i słowa kluczowe:

ochrona środowiska ; inżynieria środowiska ; czasopisma

Opis:

Environment Protection Engineering. Vol. 44, 2018, nr 4, s. 117-129

Abstrakt:

Adsorption studies were conducted to assess the feasibility of ferric hydroxide-based material for treatment of highly arsenic-contaminated effluents. The experiments were performed in a batch adsorption regime using a synthetic aqueous solution. The contact time between arsenic ions and the adsorbent, initial concentration of arsenic in treated solution, temperature of solution and adsorbent dose had a significant effect on the adsorption performance in the system. Both the mechanism of the process involved and the rate of As(III) and As(V) adsorption were analyzed based on pseudo-firstand pseudo-second order kinetic models. The adsorption data at constant temperature were described by the Langmuir and Freundlich isotherm equation, and the theoretical adsorption capacity of ferric hydroxide was determined to be 43.75 mg/g and 44.04 mg/g for arsenic(III) and (V), respectively. The estimated thermodynamic parameters, including changes in free energy, enthalpy and entropy, revealed that the adsorption is spontaneous and endothermic under applied experimental conditions.

Wydawca:

Oficyna Wydawnicza Politechniki Wrocławskiej

Miejsce wydania:

Wrocław

Data wydania:

2018

Typ zasobu:

artykuł

Identyfikator zasobu:

doi:10.5277/epe180408

Źródło:

<sygn. PWr A4232I> ; kliknij tutaj, żeby przejść ; kliknij tutaj, żeby przejść

Język:

eng

Powiązania:

Environment Protection Engineering ; Environment Protection Engineering. Vol. 44, 2018 ; Environment Protection Engineering. Vol. 44, 2018, nr 4

Prawa:

Wszystkie prawa zastrzeżone (Copyright)

Prawa dostępu:

Dla wszystkich w zakresie dozwolonego użytku

Lokalizacja oryginału:

Politechnika Wrocławska